technicalsymposium

Email Alert & Search in Our Website


Email ID:

(Note:Login & Check Your Email Inbox and Activate Confirmation Link)

Free Email Alerts-Subscribe

Email :
Check Inbox & Activate Confirmation Link
Any Doubt in our website-Search & Get Details


Free Event Publishing

Publishing your Event with us
& Reach more audience

Get Free Publishing
Close Box

GATE 2018 Syllabus-Chemistry

GATE 2018 Syllabus-Chemistry

Section 1: Physical Chemistry

Structure: Postulates of quantum mechanics. Time dependent and time independent Schrödinger equations. Born interpretation. Particle in a box. Harmonic oscillator. Rigid rotor. Hydrogen atom: atomic orbitals. Multi-electron atoms: orbital approximation. Variation and first order perturbation techniques. Chemical bonding: Valence bond theory and LCAO-MO theory. Hybrid orbitals. Applications of LCAO-MOT to H2+, H2 and other homonuclear diatomic molecules, heteronuclear diatomic molecules like HF, CO, NO, and to simple delocalized p– electron systems. Hückel approximation and its application to annular p – electron systems. Symmetry elements and operations. Point groups and character tables. Origin of selection rules for rotational, vibrational, electronic and Raman spectroscopy of diatomic and polyatomic molecules. Einstein coefficients. Relationship of transition moment integral with molar extinction coefficient and oscillator strength. Basic principles of nuclear magnetic resonance: nuclear g factor, chemical shift, nuclear coupling.

Equilibrium: Laws of thermodynamics. Standard states. Thermochemistry. Thermodynamic functions and their relationships: Gibbs-Helmholtz and Maxwell relations, van’t Hoff equation. Criteria of spontaneity and equilibrium. Absolute entropy. Partial molar quantities. Thermodynamics of mixing. Chemical potential. Fugacity, activity and activity coefficients. Chemical equilibria. Dependence of equilibrium constant on temperature and pressure. Non-ideal solutions. Ionic mobility and conductivity. Debye-Hückel limiting law. Debye-Hückel-Onsager equation. Standard electrode potentials and electrochemical cells. Potentiometric and conductometric titrations. Phase rule. Clausius-Clapeyron equation. Phase diagram of one component systems: CO2, H2O, S; two component systems: liquid-vapour, liquid-liquid and solid-liquid systems. Fractional distillation. Azeotropes and eutectics. Statistical thermodynamics: microcanonical and canonical ensembles, Boltzmann distribution, partition functions and thermodynamic properties.

Kinetics: Transition state theory: Eyring equation, thermodynamic aspects. Potential energy surfaces and classical trajectories. Elementary, parallel, opposing and consecutive reactions. Steady state approximation. Mechanisms of complex reactions. Unimolecular reactions. Kinetics of polymerization and enzyme catalysis. Fast reaction kinetics: relaxation and flow methods. Kinetics of photochemical and photophysical processes.

Surfaces and Interfaces: Physisorption and chemisorption. Langmuir, Freundlich and BET isotherms. Surface catalysis: Langmuir-Hinshelwood mechanism. Surface tension, viscosity. Self-assembly. Physical chemistry of colloids, micelles and macromolecules.

Section 2: Inorganic Chemistry

Main Group Elements: Hydrides, halides, oxides, oxoacids, nitrides, sulfides – shapes and reactivity. Structure and bonding of boranes, carboranes, silicones, silicates, boron nitride, borazines and phosphazenes. Allotropes of carbon. Chemistry of noble gases, pseudohalogens, and interhalogen compounds. Acid-base concepts.

Transition Elements: Coordination chemistry – structure and isomerism, theories of bonding (VBT, CFT, and MOT). Energy level diagrams in various crystal fields, CFSE, applications of CFT, Jahn-Teller distortion. Electronic spectra of transition metal complexes: spectroscopic term symbols, selection rules, Orgel diagrams, charge-transfer spectra. Magnetic

properties of transition metal complexes. Reaction mechanisms: kinetic and thermodynamic stability, substitution and redox reactions.

Lanthanides and Actinides: Recovery. Periodic properties, spectra and magnetic properties.

Organometallics: 18-Electron rule; metal-alkyl, metal-carbonyl, metal-olefin and metal-carbene complexes and metallocenes. Fluxionality in organometallic complexes. Types of organometallic reactions. Homogeneous catalysis - Hydrogenation, hydroformylation, acetic acid synthesis, metathesis and olefin oxidation. Heterogeneous catalysis - Fischer-Tropsch reaction, Ziegler-Natta polymerization.

Radioactivity: Decay processes, half-life of radioactive elements, fission and fusion processes.

Bioinorganic Chemistry: Ion (Na+ and K+) transport, oxygen binding, transport and utilization, electron transfer reactions, nitrogen fixation, metalloenzymes containing magnesium, molybdenum, iron, cobalt, copper and zinc.

Solids: Crystal systems and lattices, Miller planes, crystal packing, crystal defects, Bragg’s law, ionic crystals, structures of AX, AX2, ABX3 type compounds, spinels, band theory, metals and semiconductors.

Instrumental Methods of Analysis: UV-visible spectrophotometry, NMR and ESR spectroscopy, mass spectrometry. Chromatography including GC and HPLC. Electroanalytical methods- polarography, cyclic voltammetry, ion-selective electrodes. Thermoanalytical methods.

Section 3: Organic Chemistry

Stereochemistry: Chirality of organic molecules with or without chiral centres and determination of their absolute configurations. Relative stereochemistry in compounds having more than one stereogenic centre. Homotopic, enantiotopic and diastereotopic atoms, groups and faces. Stereoselective and stereospecific synthesis. Conformational analysis of acyclic and cyclic compounds. Geometrical isomerism. Configurational and conformational effects, and neighbouring group participation on reactivity and selectivity/specificity.

Reaction Mechanisms: Basic mechanistic concepts – kinetic versus thermodynamic control, Hammond’s postulate and Curtin-Hammett principle. Methods of determining reaction mechanisms through identification of products, intermediates and isotopic labeling. Nucleophilic and electrophilic substitution reactions (both aromatic and aliphatic). Addition reactions to carbon-carbon and carbon-heteroatom (N,O) multiple bonds. Elimination reactions. Reactive intermediates – carbocations, carbanions, carbenes, nitrenes, arynes and free radicals. Molecular rearrangements involving electron deficient atoms.

Organic Synthesis: Synthesis, reactions, mechanisms and selectivity involving the following classes of compounds – alkenes, alkynes, arenes, alcohols, phenols, aldehydes, ketones, carboxylic acids, esters, nitriles, halides, nitro compounds, amines and amides. Uses of Mg, Li, Cu, B, Zn and Si based reagents in organic synthesis. Carbon-carbon bond formation through coupling reactions - Heck, Suzuki, Stille and Sonogoshira. Concepts of multistep

synthesis - retrosynthetic analysis, strategic disconnections, synthons and synthetic equivalents. Umpolung reactivity – formyl and acyl anion equivalents. Selectivity in organic synthesis – chemo-, regio- and stereoselectivity. Protection and deprotection of functional groups. Concepts of asymmetric synthesis – resolution (including enzymatic), desymmetrization and use of chiral auxilliaries. Carbon-carbon bond forming reactions through enolates (including boron enolates), enamines and silyl enol ethers. Michael addition reaction. Stereoselective addition to C=O groups (Cram and Felkin-Anh models).

Pericyclic Reactions and Photochemistry: Electrocyclic, cycloaddition and sigmatropic reactions. Orbital correlations - FMO and PMO treatments. Photochemistry of alkenes, arenes and carbonyl compounds. Photooxidation and photoreduction. Di-p-methane rearrangement, Barton reaction.

Heterocyclic Compounds: Structure, preparation, properties and reactions of furan, pyrrole, thiophene, pyridine, indole, quinoline and isoquinoline.

Biomolecules: Structure, properties and reactions of mono- and di-saccharides, physicochemical properties of amino acids, chemical synthesis of peptides, structural features of proteins, nucleic acids, steroids, terpenoids, carotenoids, and alkaloids.

Spectroscopy: Applications of UV-visible, IR, NMR and Mass spectrometry in the structural determination of organic molecules.

GATE 2018 Syllabus-Chemistry -Click here to Download

Technical Symposium.Com All Jobs & Certifications
Lecture Notes and Scholarships & Project Details

Fresher Jobs Details
job detailsAll Fresher Software Jobs Details
job detailsAll Government Jobs Details
job detailsAll Internships Details
job detailsOff-Campus Interviews/Walk-in Details
job detailsAll Competitive Exam Details
job detailsBank Clerk/Officers Jobs Details
job detailsB.Sc/M.Sc Graduate Fresher Jobs
job detailsAll Technical Jobs Details
job detailsAll State/Central Government Jobs Details
Conference/Symposium Details
job detailsAll International Conference Details
job detailsAll National Conference Details
job detailsAll Symposium/Workshop Details
job detailsUniversity Conferences Details
job detailsIIT/NIT/IIM Conference Details
job detailsComputer Science Conference Details
job detailsElectronics Conferences Details
job detailsMechanical Conferences Details
job detailsAll Latest Conferences Details
Calendar of Events Details
job detailsJanuary – List of All Event Details
job detailsFebruary – List of All Event Details
job detailsMarch– List of All Event Details
job detailsApril – List of All Event Details
job detailsMay – List of All Event Details
job detailsJune – List of All Event Details
job detailsJuly – List of All Event Details
job detailsAugust – List of All Event Details
job detailsAll Months - List of All Events Details
GATE Question Papers & Syllabus
job detailsAll GATE Previous Year Question Papers
job detailsGATE Syllabus for All Branches
job detailsGATE-Computer Science Question Papers
job detailsGATE – Mechanical Question Papers
job detailsGATE – ECE Question Papers
job detailsGATE- EEE Question Papers
job detailsGATE – Civil Engineering Question Papers
job detailsGATE – All Branches Question Papers
job detailsGATE Exam Pattern Details
IES Question Papers & Syllabus
job detailsIES Complete Information
job detailsIES Previous Year Question Papers
job detailsIES Syllabus for All Branches
job detailsIES – Mechanical Question Papers
job detailsIES - E & T Question Papers
job detailsIES - EEE Question Papers
job detailsIES -Civil Engineering Question Papers
job detailsIES - All Branches Question Papers
job detailsIES - Exam Pattern Details
All Companies Placement Materials
job detailsTCS Placement Papers
job detailsWIPRO Placement Papers
job detailsZOHO Placement Papers
job detailsCTS Placement Papers
job detailsINFOSYS Placement Papers
job detailsARICENT Placement Papers
job detailsSBI Placement Papers
job detailsRRB Placement Papers
job detailsBANK/IBPS Placement Papers
Aptitude Round Materials
job details Problem on Numbers
job detailsProblem on Trains
job detailsTime and Work
job detailsSimple Interest
job detailsAptitude Short- Cut Formulas
job detailsAptitude Tricks
job detailsOdd Man Out Series
job detailsSimplification Problems
job detailsProfit & Loss
Technical Round Materials
job detailsJAVA Technical Round Q & A
job detailsC Technical Round Q & A
job detailsC++ Technical Round Q & A
job detailsASP.NET Technical Round Q & A
job detailsData Structure Technical Round Q & A
job detailsSQL Technical Round Q & A
job detailsC# Technical Round Q & A
job detailsPHP Technical Round Q & A
job detailsJ2EE Technical Round Q & A
Software Programs and Lab Manuals
job detailsSurvey Lab Manuals
job detailsCAD/CAM Lab Manuals
job detailsOOPS/C++ Lab Manuals
job detailsJAVA/Internet Programming Manuals
job detailsList of All C Programs with Source Code
job detailsList of All Data Structure Programs
job detailsC Aptitude Programs
job detailsMicroprocessor & Micro Controller Manuals
job detailsAll Engineering Branches Lab Manuals
Anna University Syllabus & Question Papers
job detailsB.E/B.Tech Previous Year Question Papers
job detailsBE-Computer Science Syllabus
job detailsBE-Mechanical Engineering Syllabus
job detailsBE-Civil Engineering Syllabus
job detailsBE-ECE Syllabus
job detailsBE-EEE Syllabus
job detailsMBA/MCA Syllabus
job detailsBE-Aeronautical Engineering Syllabus
job detailsBE-Biomedical Syllabus
IBPS/Bank Syllabus & Question Papers
job detailsIBPS Clerk Exam Syllabus
job detailsIBPS Clerk Question Papers
job detailsIBPS Probationary Officers Syllabus
job detailsIBPS PO Question Papers
job detailsIBPS RRB Exam Syllabus
job detailsIBPS Special Officers Exam Syllabus
job detailsSBI Clerk/PO Syllabus
job detailsAll Private Banks PO/Clerk Syllabuses
job detailsAll Nationalized Bank Po/Clerk Syllabuses
Civil Engineering Lecture Notes
job detailsFirst Semester Lecture Notes
job detailsSecond Semester Lecture Notes
job detailsThird Semester Lecture Notes
job detailsFourth Semester Lecture Notes
job detailsFifth Semester Lecture Notes
job detailsSixth Semester Lecture Notes
job detailsSeventh Semester Lecture Notes
job detailsEighth Semester Lecture Notes
job detailsLab Manuals
Mechanical Engineering Lecture Notes
job detailsFirst Semester Lecture Notes
job detailsSecond Semester Lecture Notes
job detailsThird Semester Lecture Notes
job detailsFourth Semester Lecture Notes
job detailsFifth Semester Lecture Notes
job detailsSixth Semester Lecture Notes
job detailsSeventh Semester Lecture Notes
job detailsEighth Semester Lecture Notes
job detailsLab Manuals
Computer Science Engineering Lecture Notes
job detailsFirst Semester Lecture Notes
job detailsSecond Semester Lecture Notes
job detailsThird Semester Lecture Notes
job detailsFourth Semester Lecture Notes
job detailsFifth Semester Lecture Notes
job detailsSixth Semester Lecture Notes
job detailsSeventh Semester Lecture Notes
job detailsEighth Semester Lecture Notes
job detailsLab Manuals
MCA Lecture Notes
job detailsFirst Semester Lecture Notes
job detailsSecond Semester Lecture Notes
job detailsThird Semester Lecture Notes
job detailsFourth Semester Lecture Notes
job detailsFifth Semester Lecture Notes
job detailsSixth Semester Lecture Notes
job detailsSeventh Semester Lecture Notes
job detailsEighth Semester Lecture Notes
job detailsLab Manuals
MBA Lecture Notes
job detailsFirst Semester Lecture Notes
job detailsSecond Semester Lecture Notes
job detailsThird Semester Lecture Notes
job detailsFourth Semester Lecture Notes
job detailsFifth Semester Lecture Notes
job detailsSixth Semester Lecture Notes
job detailsSeventh Semester Lecture Notes
job detailsEighth Semester Lecture Notes
job detailsLab Manuals
ECE Lecture Notes
job detailsFirst Semester Lecture Notes
job detailsSecond Semester Lecture Notes
job detailsThird Semester Lecture Notes
job detailsFourth Semester Lecture Notes
job detailsFifth Semester Lecture Notes
job detailsSixth Semester Lecture Notes
job detailsSeventh Semester Lecture Notes
job detailsEighth Semester Lecture Notes
job detailsLab Manuals
EEE Lecture Notes
job detailsFirst Semester Lecture Notes
job detailsSecond Semester Lecture Notes
job detailsThird Semester Lecture Notes
job detailsFourth Semester Lecture Notes
job detailsFifth Semester Lecture Notes
job detailsSixth Semester Lecture Notes
job detailsSeventh Semester Lecture Notes
job detailsEighth Semester Lecture Notes
job detailsLab Manuals
Biotechnology Lecture Notes
job detailsFirst Semester Lecture Notes
job detailsSecond Semester Lecture Notes
job detailsThird Semester Lecture Notes
job detailsFourth Semester Lecture Notes
job detailsFifth Semester Lecture Notes
job detailsSixth Semester Lecture Notes
job detailsSeventh Semester Lecture Notes
job detailsEighth Semester Lecture Notes
job detailsLab Manuals
Chemical Engineering Lecture Notes
job detailsFirst Semester Lecture Notes
job detailsSecond Semester Lecture Notes
job detailsThird Semester Lecture Notes
job detailsFourth Semester Lecture Notes
job detailsFifth Semester Lecture Notes
job detailsSixth Semester Lecture Notes
job detailsSeventh Semester Lecture Notes
job detailsEighth Semester Lecture Notes
job detailsLab Manuals
Biomedical Engineering Lecture Notes
job detailsFirst Semester Lecture Notes
job detailsSecond Semester Lecture Notes
job detailsThird Semester Lecture Notes
job detailsFourth Semester Lecture Notes
job detailsFifth Semester Lecture Notes
job detailsSixth Semester Lecture Notes
job detailsSeventh Semester Lecture Notes
job detailsEighth Semester Lecture Notes
job detailsLab Manuals
Aeronautical Engineering Lecture Notes
job detailsFirst Semester Lecture Notes
job detailsSecond Semester Lecture Notes
job detailsThird Semester Lecture Notes
job detailsFourth Semester Lecture Notes
job detailsFifth Semester Lecture Notes
job detailsSixth Semester Lecture Notes
job detailsSeventh Semester Lecture Notes
job detailsEighth Semester Lecture Notes
job detailsLab Manuals
B.Sc (All Major Branches) Lecture Notes
job detailsMaths / Statistics Lecture Notes
job detailsPhysics Lecture Notes
job detailsChemistry Lecture Notes
job detailsElectronics Lecture Notes
job detailsComputer Science/IT Lecture Notes
job detailsAgriculture Lecture Notes
job detailsBiotechnology/Biomedical Lecture Notes
job detailsNursing Lecture Notes
job detailsFashion Technology Lecture Notes
M.Sc (All Major Branches) Lecture Notes
job detailsComputer Science/IT Lecture Notes
job detailsAgriculture Lecture Notes
job detailsBiotechnology/Biomedical Lecture Notes
job detailsNursing Lecture Notes
job detailsFashion Technology Lecture Notes
job detailsMaths / Statistics Lecture Notes
job detailsPhysics Lecture Notes
job detailsChemistry Lecture Notes
job detailsElectronics Lecture Notes
B.Com/M.Com Lecture Notes
job detailsFirst Semester Lecture Notes
job detailsSecond Semester Lecture Notes
job detailsThird Semester Lecture Notes
job detailsFourth Semester Lecture Notes
job detailsFifth Semester Lecture Notes
job detailsSixth Semester Lecture Notes
job detailsLab Manuals
job detailsCommerce Placement Materials
job detailsCommerce Placement Materials
BBA Lecture Notes
job detailsFirst Semester Lecture Notes
job detailsSecond Semester Lecture Notes
job detailsThird Semester Lecture Notes
job detailsFourth Semester Lecture Notes
job detailsFifth Semester Lecture Notes
job detailsSixth Semester Lecture Notes
job detailsLab Manuals
job detailsPlacement MaterialsEighth Semester Lecture Notes
job detailsFresher Jobs Details
BCA Lecture Notes
job detailsFirst Semester Lecture Notes
job detailsSecond Semester Lecture Notes
job detailsThird Semester Lecture Notes
job detailsFourth Semester Lecture Notes
job detailsFifth Semester Lecture Notes
job detailsSixth Semester Lecture Notes
job detailsLab Manuals
job detailsPlacement Materials
job detailsFresher Jobs Details

Hosting by Yahoo!

About-Us    Contact-Us    Site-map

©copyright All rights are reserved to technicalsymposium.com